A burning question : structural and isotopic analysis of cremated bone in archaeological contexts
Cremated bone occurs in many archaeological sites as small grey and white fragments. The high temperatures reached during heating induce structural, chemical and isotopic changes to bone apatite (the inorganic fraction of bone). These changes are investigated here by infrared spectroscopy and mass spectrometry (d13C, d18O and 87Sr/86Sr) in both modern heated bone and archaeological cremated specimens. The results of various heating experiments (in laboratory and natural conditions) highlight the significant carbon and oxygen exchanges with the fuel used as well as with bone organic matter (mainly collagen). While not informing on dietary practice and hydrology as is the case with unburned bone, the d13C and d18O values of calcined samples together with infrared results provide information on the conditions in which the bone was heated (e.g. presence of fuel, size of the pyre, temperatures reached, dry or fresh bone, etc.). In parallel, the effect of heat on the strontium present in bone is minimal, if not undetectable. Furthermore, as observed through artificial contamination experiments, post-burial alterations also appear to be extremely limited, which is to be expected due to the higher crystallinity of
Snoeck, Christophe
Human remains (Archaeology)--Analysis ; Bone--Analysis ; Cremation ; Stable isotopes ; Neolithic period--Ireland ; Bronze age--Ireland ; Archaeological chemistry ; Ireland--Antiquities ; Prehistoric
A burning question : structural and isotopic analysis of cremated bone in archaeological contexts. Cremated bone occurs in many archaeological sites as small grey and white fragments. The high temperatures reached during heating induce structural, chemical and isotopic changes to bone apatite (the inorganic fraction of bone). These changes are investigated here by infrared spectroscopy and mass spectrometry (d13C, d18O and 87Sr/86Sr) in both modern heated bone and archaeological cremated specimens. The results of various heating experiments (in laboratory and natural conditions) highlight the significant carbon and oxygen exchanges with the fuel used as well as with bone organic matter (mainly collagen). While not informing on dietary practice and hydrology as is the case with unburned bone, the d13C and d18O values of calcined samples together with infrared results provide information on the conditions in which the bone was heated (e.g. presence of fuel, size of the pyre, temperatures reached, dry or fresh bone, etc.). In parallel, the effect of heat on the strontium present in bone is minimal, if not undetectable. Furthermore, as observed through artificial contamination experiments, post-burial alterations also appear to be extremely limited, which is to be expected due to the higher crystallinity of
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